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Low pH Stability vs High pH Swing

by Brian Dunleavy
Low pH Stability vs High pH Swing

pH is one of those parameters that reef keepers either obsess over or don’t think about at all. And if you’ve spent any time on the forums, you’ll know the debate around it can get heated quickly. One of the most interesting, and truly useful, conversations in the hobby is based around a particular question: Is a steady low pH worse for your reef than a pH that swings wildly but reaches higher levels during the day?

It’s a question worth looking into properly, as the answer could change the way you manage your tank.


What causes pH swings in your reef tank

Before we dive into the debate, it helps to understand why pH moves in the first place. In reef aquariums, pH goes up during the day and down during the night. The day-to-day change is due to the biological activity of photosynthesis and respiration.

 

 

Photosynthesis consumes CO2 during the day, increasing the pH; respiration produces CO2 all the time, but especially at night when photosynthesis is not compensating for it.

This diurnal fluctuation can range from less than a tenth of a pH unit to over 0.5 pH units in a typical aquarium. So some swing is expected. What matters is how big that swing is and where the low point lands.


The importance of pH stability

Traditionally, the hobby has seen stability as king. The logic is simple. Corals and your tank organisms like predictable and consistent conditions. Stress is caused by rapid swings in any parameter, and pH is no different.

Many reefers have discovered that pH stability is more important than the number itself. Research suggests that maintaining pH toward the upper end of the normal range can increase coral calcification rates, although stability remains important and chasing high pH is rarely necessary. The recommendation below is for hobbyists to minimize swings rather than chase a specific high number, which can often be difficult to achieve.

Don’t forget the important relationship between pH and alkalinity. Although alkalinity remains relatively constant, the proportion of carbonate and bicarbonate available changes as pH changes, affecting the chemistry available for calcification. This leads us to a practical question: why keep alkalinity stable when pH can fluctuate wildly from one day to the next? The two parameters are so intricately linked that you’ll only get so far managing one without regard to the other. 


The Case for Swinging When the High Point is High Enough

Here’s where it gets interesting. Many experienced reef keepers argue that a chronically low pH may be more limiting to coral health than a moderate daily pH swing, provided the swing remains within a reasonable range.

Many experienced reef keepers believe that a chronically low pH may be more limiting to coral health than a moderate daily pH swing that returns to healthy daytime values. The logic is that even though the dip at night is quite significant, during the day, when photosynthesis is in full swing and the pH is high, corals and other organisms get the benefit of ideal conditions for growth and calcification. 

 

 

Many natural reefs experience daily pH fluctuations, typically between about 7.8 and 8.3, depending on location, water movement, and biological activity. Many hobbyists maintain successful tanks with day-night swings of 0.4 pH units, provided the tank is well aerated and indoor CO2 levels are reasonable. The key phrase there is "well aerated." Chronically low pH is often a sign of poor gas exchange or elevated indoor CO2, so improving aeration is usually a better first step than reaching for additives.


What is an acceptable pH range?

Most reefers who have worked with pH agree on a general framework: changes in pH from day to day that are within the range of 7.8 to 8.4 are not particularly stressful for the majority of reef organisms. Some experienced reef chemists argue that a stable pH of 7.9 may be less desirable than a pH that naturally fluctuates between roughly 8.0 and 8.4.

For most mixed reef and SPS tanks, a reasonable goal is a daytime peak of 8.2-8.4 and a night-time low no worse than 7.9-8.0, in practical terms. A swing of .3-.4 during the day is normal and manageable. So when it is below 7.9, and it does not swing back up during the day, or when swings are bigger than 0.5, it is time to look further and closely monitor the pH with a pH probe

 


How to Increase pH Without Chasing Numbers?

If your pH is dropping or fluctuating too much, here are a few practical steps to take before you go down the route of pH buffers or additives.

One reason is that the indoor air has a high content of CO2, especially in winter when the air exchange rate is lower. The best way to run your skimmer is on fresh air from outside the house. Protein skimmers promote excellent gas exchange, so supplying them with fresh outdoor air can significantly reduce dissolved CO2.

Another popular method is a refugium that runs on an opposite light schedule. Growing macroalgae in a refugium lit during the night part of the tank cycle can help reduce the natural nighttime pH drop by continuing photosynthesis while the display tank is dark.

 

 

Many reefers love Kalkwasser because it not only supplements calcium and alkalinity, but it also raises pH because it consumes CO2 as it reacts in seawater, especially when dosed at night. It won't fit every system, but used wisely, it can help to stabilize pH in a significant way.

One simple factor that is often overlooked is that good surface agitation and adequate water movement help maximize gas exchange and prevent CO2 from accumulating in the water.


Conclusion

The evidence suggests that the low pH vs high swing debate is this: It depends on where the swing lands. The most probable scenario for problems over time is a stable but chronically low pH. A daily swing that returns to healthy daytime values and doesn’t crash too hard overnight is in many ways a more natural pattern and one your corals are better equipped to handle.

Before chasing specific numbers, focus on good husbandry, aeration, flow, and lighting. And if you're ever unsure how your tank is progressing, get in touch with the Reefco Aquariums team. We’re glad to help you understand what your parameters are telling you.

by Brian Dunleavy